diff --git a/storage/merge.go b/storage/merge.go
index 2424b26ab7..a4d0934b16 100644
--- a/storage/merge.go
+++ b/storage/merge.go
@@ -153,13 +153,18 @@ func (q *mergeGenericQuerier) Select(ctx context.Context, sortSeries bool, hints
 	)
 	// Schedule all Selects for all queriers we know about.
 	for _, querier := range q.queriers {
+		// copy the matchers as some queriers may alter the slice.
+		// See https://github.com/prometheus/prometheus/issues/14723
+		matchersCopy := make([]*labels.Matcher, len(matchers))
+		copy(matchersCopy, matchers)
+
 		wg.Add(1)
-		go func(qr genericQuerier) {
+		go func(qr genericQuerier, m []*labels.Matcher) {
 			defer wg.Done()
 
 			// We need to sort for NewMergeSeriesSet to work.
-			seriesSetChan <- qr.Select(ctx, true, hints, matchers...)
-		}(querier)
+			seriesSetChan <- qr.Select(ctx, true, hints, m...)
+		}(querier, matchersCopy)
 	}
 	go func() {
 		wg.Wait()
diff --git a/tsdb/querier_test.go b/tsdb/querier_test.go
index 77772937a7..aca6c845b1 100644
--- a/tsdb/querier_test.go
+++ b/tsdb/querier_test.go
@@ -3787,3 +3787,35 @@ func (m mockReaderOfLabels) Series(storage.SeriesRef, *labels.ScratchBuilder, *[
 func (m mockReaderOfLabels) Symbols() index.StringIter {
 	panic("Series called")
 }
+
+// TestMergeQuerierConcurrentSelectMatchers reproduces the data race bug from
+// https://github.com/prometheus/prometheus/issues/14723, when one of the queriers (blockQuerier in this case)
+// alters the passed matchers.
+func TestMergeQuerierConcurrentSelectMatchers(t *testing.T) {
+	block, err := OpenBlock(nil, createBlock(t, t.TempDir(), genSeries(1, 1, 0, 1)), nil)
+	require.NoError(t, err)
+	defer func() {
+		require.NoError(t, block.Close())
+	}()
+	p, err := NewBlockQuerier(block, 0, 1)
+	require.NoError(t, err)
+
+	// A secondary querier is required to enable concurrent select; a blockQuerier is used for simplicity.
+	s, err := NewBlockQuerier(block, 0, 1)
+	require.NoError(t, err)
+
+	originalMatchers := []*labels.Matcher{
+		labels.MustNewMatcher(labels.MatchRegexp, "baz", ".*"),
+		labels.MustNewMatcher(labels.MatchEqual, "foo", "bar"),
+	}
+	matchers := append([]*labels.Matcher{}, originalMatchers...)
+
+	mergedQuerier := storage.NewMergeQuerier([]storage.Querier{p}, []storage.Querier{s}, storage.ChainedSeriesMerge)
+	defer func() {
+		require.NoError(t, mergedQuerier.Close())
+	}()
+
+	mergedQuerier.Select(context.Background(), false, nil, matchers...)
+
+	require.Equal(t, originalMatchers, matchers)
+}